Abstract
Manganese oxide nanocrystals are of great interest for producing advanced high-performance lithium ion batteries owing to the shortened lithium ion diffusion length and accelerated interfacial charge transfer rate. Here we have developed a well-controlled generic method to synthesize monodisperse MnO nanocrystals, and present a comparative study regarding the effect of crystallite size on electrochemical stability. Nanocrystalline MnO with a size of about 10 nm shows the optimal lithium-storage performance. Notably, Mn-based nanocrystals retain their stable cyclability and excellent high-rate performance as both the anode and cathode. The all-nanocrystal MnO/C//LMO Li-ion full cells not only significantly improve the electrochemical properties of Mn-based materials but also open up avenues for the future development of various energy devices.